Electrochemical Dehydrogenative C−H Aminomethylation of Imidazopyridines and Related Heterocycles

A facile and environmentally friendly electrochemical protocol is herein reported for the C(sp²)−C(sp³) cross dehydrogenative coupling between imidazopyridines and N,N-dimethylanilines. The broad functional group compatibility includes halogens, ester, alcohol, sulfone as well as thiophene. This methodology is also suitable for benzo[d]imidazo[2,1-b]thiazole, thiazoimidazole and tetrahydroisoquinoline, and can be scaled up to 5 mmol. Mechanistic insights are discussed.     

Stability of the equilibrium of rotating drillstrings

The quasistatic stability of a rotating drillstring under longitudinal force and torque is analyzed. Constitutive equations are derived, and a technique to solve them is proposed. It is shown that the buckling mode of the drillstring is helical within a section subjected to compressive forces __________ Translated from Prikladnaya Mekhanika, Vol. 42, No. 6, pp. 101–109, June 2006.     

湍流的诱导及其对瓦斯爆炸过程中火焰和爆炸波的作用

在实验的基础上,研究了管内瓦斯爆炸过程中湍流的诱导及其对瓦斯爆炸过程中火焰和爆炸波的影响作用.研究结果表明,管道面积突变对瓦斯爆炸过程中湍流的产生具有重要影响.管道面积突变(变大、变小)时,产生附加湍流,并使下游火焰气流的湍流度增加,瓦斯爆炸过程中火焰的传播速度迅速提高,并可诱导激波的产生.在80×80mm等截面直管中(瓦斯浓度为理论上最猛烈的爆炸浓度9.5%),瓦斯爆炸最大火焰传播速度为40.8m/s,管内各点均为压力波信号,当管道加装一Φ300mm圆管形成面积突扩11倍和突缩11倍两断面后,面积突扩处(L/D=22)火焰速度增大5.05倍,达到64.4m/s,面积突缩处(L/D=28)火焰速度为156.0m/s, 增大4.55倍,并在L/D=48倍处形成激波(超压1.6976atm、波速416.7m/s),在L/D=98倍处,激波强度最大.在面积突变管内加装加速环可使瓦斯爆炸过程中湍流度加剧,火焰的传播速度更高,激波生成的位置(L/D=28)、最强点位置(L/D=70)均前移,激波强度增大.研究结果对指导现场如何防治瓦斯爆炸,减轻瓦斯爆炸的威力具有一定的指导意义.     

钢筋混凝土圆形截面非均匀配筋的图算法

圆形截面是工程中常使用的截面形式之一,但圆形截面的配筋计算较为困难,存在双重非线性(材料和截面宽度变化的非线性),《混凝土结构设计规范》给出了计算均匀配筋的超越方程组,且须迭代求解,无法手算.另外,一些圆形截面构件(如桥墩、桩基的预制桩和灌注桩等)的截面尺寸大,构件长,钢筋用量大,若采用均匀布置的配筋方式,中性轴附近的钢筋应力小,强度利用率低,经济性差.若采用非均匀配筋,在远离中性轴的外围区域布置受力钢筋,可大幅节省钢筋用量,且能充分利用钢筋及混凝土的强度.为此本文通过应变计算应力,再计算出内力的方法推导计算圆形截面配筋的公式,并将计算结果绘制成了能计算配筋的无量纲诺模图,由此可快速手算配筋,该图通用性强,可用于任意直径大小及C50以下的混凝土强度等级,是一能快速计算配筋的实用工具.     

Nonlinear interactions and chaotic dynamics of suspended cables with three-to-one internal resonances

Nonlinear planar oscillations of suspended cables subjected to external excitations with three-to-one internal resonances are investigated. At first, the Galerkin method is used to discretize the governing nonlinear integral–partial-differential equation. Then, the method of multiple scales is applied to obtain the modulation equations in the case of primary resonance. The equilibrium solutions, the periodic solutions and chaotic solutions of the modulation equations are also investigated. The Newton–Raphson method and the pseudo-arclength path-following algorithm are used to obtain the frequency/force–response curves. The supercritical Hopf bifurcations are found in these curves. Choosing these bifurcations as the initial points and applying the shooting method and the pseudo-arclength path-following algorithm, the periodic solution branches are obtained. At the same time, the Floquet theory is used to determine the stability of the periodic solutions. Numerical simulations are used to illustrate the cascades of period-doubling bifurcations leading to chaos. At last, the nonlinear responses of the two-degree-of-freedom model are investigated.     

有应力史差非匀质截面轴心受压杆的性能研究

对有应力史差、非匀质、非线弹性的轴心受压构件进行了理论分析和试验研究，初步揭示了此类构件的受力特点．理论分析和试验表明：此类构件截面承载力不是各部分材料承载力的简单叠加；承载力和截面破坏控制点因截面上材料的本构关系的变化和应力史差而发生改变．     

二维微裂纹体有效性质之间的关联研究

通过解析和数值的方法研究了二维微裂纹体有效模量和有效导电系数之间的关联，针对二维含有任意取向和平行的微裂纹介质，通过基于象素的有限元方法分别计算了它们的有效杨氏模量和有效导电系数，并建立了两种不同物理量之间的关联．研究结果表明利用简单的解析Mori-Tanaka方法也可以建立上述关联，并且与数值结果吻合很好。     

Numerical analysis of free vibrations of a beam with oscillators

The problem of free vibrations of a beam with free ends of variable cross section and mass, from which point masses (oscillators) are suspended by bars, is considered. It is shown that parametric resonances can occur in this oscillating system. Numerical examples showing the efficiency of the calculation method proposed are given. __________ Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 47, No. 4, pp. 135–144, July–August, 2006.     

黄河下游堤防地质险段研究

由地质作用影响形成的易出险堤段称为地质险段 ,主要包括活断层作用影响形成的堤基易渗漏段、强地震高发区段和地基稳定性差段等。构造节点是识别地质险段的重要的河流地貌标志之一。根据成因 ,本文将黄河下游的地质险段分为三类 ,即新构造险段、沉降险段、断裂复活险段。针对黄河下游堤防地质特征 ,圈定出东坝头、大刘屯—董口黄河南岸和路那里—十里堡黄河南岸地质险段 ,提出了治理的有关措施     

多阶变截面杆的弹性稳定计算

本文研究单阶和多阶截面杆在集中和分布轴向荷载作用下的弹性稳定计算方法,首次给出了其整体稳定和局部稳定的解析解.